Project
Cloud-Aerosol Interactions in a Nitrogen-rich Atmosphere (CAINA)
Reactive nitrogen is quickly becoming the dominant pollutant in many regions in the world, with important consequences for ecosystems, human health and climate. This leads to changes in atmospheric chemistry and physics that need to be understood in order to more effectively address this pollution. In the CAINA project we are investigating how aerosols and clouds interact in this new nitrogen-dominated chemical regime, by combining field experiments, chamber studies and modeling.
Reactive nitrogen compounds emitted from agriculture, traffic and industry are quickly becoming dominant air pollutants worldwide. This has severe consequences for air quality, ecosystems, and global climate. CAINA aims towards fully understanding the aerosol-cloud interactionsunder high reactive nitrogen concentrations. We focus on the Netherlands, where ammonia emissions from agriculture combine with NOx from industry and traffic, resulting in high concentrations of ammonium nitrate. These regularly exceed concentrations of sulfates, the main air pollutants in most other regions, by a factor of 5 or more. This makes the selected study region ideal for understanding the chemistry of the future global atmosphere.
Clouds are an important component in the life-cycle of reactive nitrogen. First, they are crucial for wet deposition of nitrogen, which has detrimental effects on vulnerable ecosystems. In addition, via chemical reactions in cloud droplets, clouds contribute to the production of nitrogen-containing inorganic (e.g., ammonium nitrate) and organic aerosol particles, with important consequences for air quality and human health. However, it is uncertain how these aqueous-phase reactions proceed under high concentrations of reactive nitrogen and at the relatively high pH values associated with nitrogen-dominated aerosols.
Clouds themselves can also be changed by nitrogen pollutants. Increases of cloud condensation nuclei (CCN) and nitric acid concentrations lead to clouds with more, but smaller droplets. This potentially results in more reflective clouds, with possible cooling effects on global climate. However, we do not yet fully understand the role of reactive nitrogen in CCN production and cloud droplet activation. Therefore, field and laboratory experiments combined with model studies are urgently needed to better understand how cloud properties are modified by reactive nitrogen pollutants.
Our consortium combines strong expertise in aerosol/cloud physics with expertise in atmospheric chemistry to answer the following research questions:
i. How are inorganic and organic pollutants produced in clouds under high reactive nitrogen concentrations?
ii. How important is this pathway for the overall air pollution in regions with high nitrogen emissions?
iii. What is the concurrent effect on cloud microphysics and cloud reflectivity?
Within the WUR team, PhD Candidate Pascale Ooms will investigate sources and gas-aerosol partitioning of reactive nitrogen species, and their effects on aerosol optical properties and cloud formation (under the supervision of Julie Fry). PhD candidate Laurie Novak will develop new chemistry and atmospheric dynamics modeling tools to simulate aerosol-cloud effects of reactive nitrogen species (under the supervision of Maarten Krol).